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Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

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Abstract

We report the synthesis and characterization of two discrete vanadoniobates, H6Cs4Na5K7[V5Nb23O80]·28H2O (1) and H6Cs4Na5K8[V6Nb23O81]·34H2O (2), based on a brand new {Nb23} and a 5/6-nuclear polyoxovanadate cap. The two vanadoniobates as heterogeneous catalysts can effectively promote the oxidative decontamination of sulfur mustard simulants.

Graphical abstract: Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

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Article information


Submitted
17 Sep 2020
Accepted
07 Oct 2020
First published
07 Oct 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Self-assembly of polyoxovanadate-capped polyoxoniobates and their catalytic decontamination of sulfur mustard simulants

N. Zhen, J. Dong, Z. Lin, X. Li, Y. Chi and C. Hu, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC06277D

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