Jump to main content
Jump to site search


Generation of alkoxysulfonyl radicals from chlorosulfates and their intramolecular capture with alkynes to obtain sultones

Author affiliations

Abstract

An unprecedented radical-mediated reaction of alkyne-containing chlorosulfates to synthesize sultones has been established. The reaction leads to the formation and subsequent capture of alkoxysulfonyl radicals, which are species known for a long time but not studied for synthetic purposes.

Graphical abstract: Generation of alkoxysulfonyl radicals from chlorosulfates and their intramolecular capture with alkynes to obtain sultones

Back to tab navigation

Supplementary files

Article information


Submitted
09 Sep 2020
Accepted
22 Sep 2020
First published
29 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Generation of alkoxysulfonyl radicals from chlorosulfates and their intramolecular capture with alkynes to obtain sultones

L. Cala, O. García-Pedrero, R. Rubio-Presa, F. J. Fañanás and F. Rodríguez, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC06098D

Social activity

Search articles by author

Spotlight

Advertisements