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Issue 81, 2020
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Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion

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Abstract

Heteroleptic copper(I) bis(phenanthroline) complexes with surface anchoring carboxylate groups have been synthesized and immobilized on nanoporous metal oxide substrates. The species investigated are responsive to the external environment and this work provides a new strategy to control charge transfer processes for efficient solar energy conversion.

Graphical abstract: Surface immobilized copper(i) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion

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Supplementary files

Article information


Submitted
03 Sep 2020
Accepted
10 Sep 2020
First published
14 Sep 2020

Chem. Commun., 2020,56, 12130-12133
Article type
Communication

Surface immobilized copper(I) diimine photosensitizers as molecular probes for elucidating the effects of confinement at interfaces for solar energy conversion

M. S. Eberhart, B. T. Phelan, J. Niklas, E. A. Sprague-Klein, D. M. Kaphan, D. J. Gosztola, L. X. Chen, D. M. Tiede, O. G. Poluektov and K. L. Mulfort, Chem. Commun., 2020, 56, 12130
DOI: 10.1039/D0CC05972B

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