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Issue 87, 2020
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Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

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Abstract

Mixed donor phenanthroline-carboxylate linkers were combined with MnII or ZnII to form photoactive MOFs with large pore apertures. The MOFs display high CO2 adsorption capacities, which consequently causes structural framework flexibility, and align with favorable metrics for selective CO2 capture. The photophysical properties of the MOFs were investigated, with the MnII MOF giving rise to short triplet LMCT lifetimes.

Graphical abstract: Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

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Supplementary files

Article information


Submitted
23 Aug 2020
Accepted
02 Sep 2020
First published
02 Sep 2020

Chem. Commun., 2020,56, 13377-13380
Article type
Communication

Mixed donor, phenanthroline photoactive MOFs with favourable CO2 selectivity

C. J. Setter, M. B. Price, L. Conte, W. Schmitt, S. R. Batten, C. Richardson, M. R. Hill, R. Babarao and L. K. Macreadie, Chem. Commun., 2020, 56, 13377
DOI: 10.1039/D0CC05715K

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