Aromaticity is one of the central concepts in chemistry and stabilizes many clusters that have interesting structural motifs. Herein, a cationic BBe6H6 cluster featuring a planar hexacoordinate boron structure stabilized by 2π/6σ double aromaticity was predicted theoretically. The cluster was predicted to be dynamically stable well above room temperature.
A. J. Kalita, S. S. Rohman, C. Kashyap, S. S. Ullah and A. K. Guha, Chem. Commun., 2020, 56, 12597 DOI: 10.1039/D0CC05668E
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