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All-metal Baird aromaticity

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Abstract

Baird's rule has been applied to a large scope of organic molecular systems for rationalizing the aromaticity reversal in the lowest-lying triplet state. In this study, we demonstrate that Baird's rule can also be extended to all-metal systems with σ- and π-aromaticity.

Graphical abstract: All-metal Baird aromaticity

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Article information


Submitted
17 Aug 2020
Accepted
07 Sep 2020
First published
07 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

All-metal Baird aromaticity

D. Chen, D. W. Szczepanik, J. Zhu and M. Solà, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC05586G

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