Jump to main content
Jump to site search


Secondary phosphine oxide-triggered selective oxygenation of a benzyl ligand on palladium

Author affiliations

Abstract

The oxygenation of a benzyl ligand in [PdBnCl(cod)] was dramatically accelerated by using secondary phosphine oxides (SPOs), selectively affording either BnOOH or BnOH, depending on the concentration of O2. The SPOs coordinate to palladium in the form of phosphinous acids, operating as Brønsted acids to facilitate further reaction with O2.

Graphical abstract: Secondary phosphine oxide-triggered selective oxygenation of a benzyl ligand on palladium

Back to tab navigation

Supplementary files

Article information


Submitted
15 Aug 2020
Accepted
17 Sep 2020
First published
17 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Secondary phosphine oxide-triggered selective oxygenation of a benzyl ligand on palladium

S. Oka, Y. Shigehiro, Y. Kataoka and Y. Ura, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC05572G

Social activity

Search articles by author

Spotlight

Advertisements