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Ln(ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising catalysts for olefin hydrophosphination

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Abstract

First Ln(II) ring-expanded NHC complexes (er-NHC)Ln[N(SiMe3)2]2 (Ln = Sm, Yb) are synthesized and proved to be highly efficient pre-catalysts for the intermolecular hydrophosphination of such indolent substrates as 1-alkenes, cyclohexene and norbornene.

Graphical abstract: Ln(ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising catalysts for olefin hydrophosphination

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Article information


Submitted
09 Aug 2020
Accepted
16 Sep 2020
First published
16 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Ln(II) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising catalysts for olefin hydrophosphination

I. V. Lapshin, A. V. Cherkasov, A. F. Asachenko and A. A. Trifonov, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC05424K

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