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Issue 91, 2020
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Hypervalent iodine reagent-mediated reactions involving rearrangement processes

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Abstract

Hypervalent iodine reagents have been extensively employed in various types of oxidative organic reactions including oxidative coupling/cyclization, bifunctionalization of olefins and cyclopropane, C–H functionalization, and oxidative rearrangement reactions. In this review, the developments of the exclusive hypervalent iodine-mediated reactions involving oxidative rearrangement processes, including [1,2]-migration, Hofmann rearrangement, Beckmann rearrangement, ring contraction, ring expansion, [3,3]-sigmatropic/iodonium-Claisen rearrangement and some miscellaneous rearrangements, have been summarized.

Graphical abstract: Hypervalent iodine reagent-mediated reactions involving rearrangement processes

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Article information


Submitted
06 Aug 2020
Accepted
30 Sep 2020
First published
01 Oct 2020

Chem. Commun., 2020,56, 14119-14136
Article type
Feature Article

Hypervalent iodine reagent-mediated reactions involving rearrangement processes

B. Zhang, X. Li, B. Guo and Y. Du, Chem. Commun., 2020, 56, 14119
DOI: 10.1039/D0CC05354F

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