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A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages

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Abstract

A Cu4L4 metal–organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline–copper coordination and possess a tunable porosity based on the rate of deprotection.

Graphical abstract: A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages

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Article information


Submitted
06 Aug 2020
Accepted
20 Sep 2020
First published
21 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages

M. L. Schneider, O. M. Linder-Patton and W. M. Bloch, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC05349J

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