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Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2 functionalization

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Abstract

Herein, we report the synthesis of a Cr(III)-complex bearing a redox non-innocent phenalenyl-based ligand and its use as a catalyst for SET mediated hydrosilylative reduction of carbon dioxide towards formylation of primary amides under mild conditions. A preliminary mechanistic picture for this transformation has been proposed by isolation and characterization of several reactive intermediates.

Graphical abstract: Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2 functionalization

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Article information


Submitted
06 Aug 2020
Accepted
29 Sep 2020
First published
29 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2 functionalization

S. Chakraborty, A. Das, J. Ahmed, S. Barman and S. K. Mandal, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC05348A

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