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Monocarboxylate-Driven Structural Growth in Calix[n]arene-Polyoxotitanate Hybrid Systems: Utility in Hydrogen Production from Water

Abstract

A carboxylate-driven assembly strategy has first been developed to build calix[n]arene-based polyoxotitanate clusters with tuneable nuclearity and structures. Photocatalytic studies revealed that those clusters exhibit structural-dependent H2 evolution ability with maximum rate up to 415.11 μmol/h/g, which is almost the highest record in polyoxotitanate clusters.

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Supplementary files

Article information


Submitted
05 Aug 2020
Accepted
15 Oct 2020
First published
15 Oct 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Communication

Monocarboxylate-Driven Structural Growth in Calix[n]arene-Polyoxotitanate Hybrid Systems: Utility in Hydrogen Production from Water

C. Liu, X. Yang, W. Yu, L. Li and X. Yi, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/D0CC05336H

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