Issue 84, 2020

PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

Abstract

An unprecedented formation of a meso-fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl2 salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores.

Graphical abstract: PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

Supplementary files

Article information

Article type
Communication
Submitted
04 Aug 2020
Accepted
14 Sep 2020
First published
15 Sep 2020

Chem. Commun., 2020,56, 12809-12812

PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

M. Murugavel, B. Adinarayana, M. Das, S. Peruncheralathan, N. R. Palepu and A. Srinivasan, Chem. Commun., 2020, 56, 12809 DOI: 10.1039/D0CC05309K

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