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Issue 84, 2020
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PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

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Abstract

An unprecedented formation of a meso-fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl2 salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores.

Graphical abstract: PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

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Article information


Submitted
04 Aug 2020
Accepted
14 Sep 2020
First published
15 Sep 2020

Chem. Commun., 2020,56, 12809-12812
Article type
Communication

PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue

M. Murugavel, B. Adinarayana, M. Das, S. Peruncheralathan, N. R. Palepu and A. Srinivasan, Chem. Commun., 2020, 56, 12809
DOI: 10.1039/D0CC05309K

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