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Issue 91, 2020
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A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction

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Abstract

We report an unprecedented dinuclear catalyst for the electrochemical hydrogen evolution reaction (HER). A macrocyclic porphyrin complex comprising two nickel centres connected via redox mediating linker molecules gives rise to efficient catalysis, significantly outperforming a mononuclear reference catalyst.

Graphical abstract: A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction

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Article information


Submitted
31 Jul 2020
Accepted
20 Oct 2020
First published
21 Oct 2020

Chem. Commun., 2020,56, 14179-14182
Article type
Communication

A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction

J. Jökel, F. Schwer, M. von Delius and U. Apfel, Chem. Commun., 2020, 56, 14179
DOI: 10.1039/D0CC05229A

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