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Biomimetic systems involving sequential redox reactions in glycolysis – the sulfur effect

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Abstract

Magnesium hemithioacetates were used as model cysteine compounds to mimic natural hemithioacetals, and their biomimetic oxidation reactions using a model NAD+ compound were investigated. Cyclic hemithioacetate was found to be the best substrate for the reaction with the model NAD+ compound, which gave the corresponding NADH analog in excellent yield.

Graphical abstract: Biomimetic systems involving sequential redox reactions in glycolysis – the sulfur effect

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Article information


Submitted
30 Jul 2020
Accepted
17 Sep 2020
First published
25 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Biomimetic systems involving sequential redox reactions in glycolysis – the sulfur effect

N. Ogawa, S. Furukawa, Y. Kosugi, T. Takazawa and N. Kanomata, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC05185C

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