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Issue 86, 2020
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Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding

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Abstract

Distance dependence of appended Lewis acids in N2H4 binding and deprotonation was evaluated within a series of zinc complexes. Variation of spacer-length to a tethered trialkylborane Lewis acid revealed distinct preferences for binding and stabilization of the resulting deprotonated N2H3 unit.

Graphical abstract: Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding

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Article information


Submitted
27 Jul 2020
Accepted
16 Sep 2020
First published
05 Oct 2020

Chem. Commun., 2020,56, 13105-13108
Article type
Communication

Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding

J. J. Kiernicki, E. E. Norwine, M. A. Lovasz, M. Zeller and N. K. Szymczak, Chem. Commun., 2020, 56, 13105
DOI: 10.1039/D0CC05121G

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