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Issue 75, 2020
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Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes

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Abstract

A divergent photocatalytic system for the reaction of α-bromo nitroalkanes with styrene derivatives is established, wherein the generation of the persistent nitroxyl radical as a junctional intermediate and suitable tuning of the redox ability of the system constitute the crucial elements for achieving rigorous control over the possible reaction pathways.

Graphical abstract: Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes

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Article information


Submitted
13 Jul 2020
Accepted
03 Aug 2020
First published
04 Aug 2020

Chem. Commun., 2020,56, 11014-11017
Article type
Communication

Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes

Y. Tsuchiya, R. Onai, D. Uraguchi and T. Ooi, Chem. Commun., 2020, 56, 11014
DOI: 10.1039/D0CC04821F

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