Issue 72, 2020
From the journal:

Chemical Communications

Solvent vapor-induced polarity and ferroelectricity switching†

Fumiya Kobayashi, ORCID logo a   Ryohei Akiyoshi, ORCID logo b   Daisuke Kosumi, ORCID logo cd   Masaaki Nakamura,b   Leonard F. Lindoy ORCID logo e  and  Shinya Hayami ORCID logo *bd  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan

b Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan
E-mail: hayami@kumamoto-u.ac.jp

c Department of Physics, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

d Institute of Industrial Nanomaterials (IINa), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

e School of Chemistry, The University of Sydney, NSW 2006, Australia

Abstract

Vapor-induced crystal to crystal transformation between non-polar [Fe(sap)(acac)(sol)] (H2sap = 2-salicylideneaminophenol, acac = acethylacetate, sol = MeOH, pyridine) and polar [Fe(sap)(acac)(DMSO)] was demonstrated. It provides an example of switchable ferroelectric behaviour attributted to the structural phase transition triggered by solvent vapour.

Graphical abstract: Solvent vapor-induced polarity and ferroelectricity switching

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Article information

DOI
https://doi.org/10.1039/D0CC04497K
Article type
Communication
Submitted
30 Jun 2020
Accepted
03 Aug 2020
First published
06 Aug 2020

Chem. Commun., 2020,56, 10509-10512

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Solvent vapor-induced polarity and ferroelectricity switching

F. Kobayashi, R. Akiyoshi, D. Kosumi, M. Nakamura, L. F. Lindoy and S. Hayami, Chem. Commun., 2020, 56, 10509 DOI: 10.1039/D0CC04497K

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