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Issue 84, 2020
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Cocrystals of Li+ encapsulated fullerenes and Tb(iii) double-decker single molecule magnet in a quasi-kagome lattice

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Abstract

Cocrystallization of a lithium ion encapsulated fullerene Li+@C60 with a terbium(III) phthalocyaninato porphyrinato double-decker single-molecule magnet [Tb(Pc)(OEP)] is reported. The cocrystal, containing PF6 as a counter anion, packs in a quasi-kagome lattice, which leads to intermolecular ferromagnetic interactions as well as the modulation of the single-molecule magnet (SMM) properties.

Graphical abstract: Cocrystals of Li+ encapsulated fullerenes and Tb(iii) double-decker single molecule magnet in a quasi-kagome lattice

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Article information


Submitted
23 Jun 2020
Accepted
13 Sep 2020
First published
15 Sep 2020

Chem. Commun., 2020,56, 12785-12788
Article type
Communication

Cocrystals of Li+ encapsulated fullerenes and Tb(III) double-decker single molecule magnet in a quasi-kagome lattice

H. Iwami, J. Xing, R. Nakanishi, Y. Horii, K. Katoh, B. K. Breedlove, K. Kawachi, Y. Kasama, E. Kwon and M. Yamashita, Chem. Commun., 2020, 56, 12785
DOI: 10.1039/D0CC04349D

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