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Liquid–liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(ii) complex

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Abstract

Porous molecular crystals (PMCs) should function as new-generation functional porous materials, but the selective crystallisation of PMCs is still difficult. Herein we demonstrate that the liquid–liquid interface between the MeOH/H2O mixture and alkanes promotes the crystallisation of a Pt(II)-based PMC, rather than the nonporous form. This new crystallisation method allows control of not only the porosity but also the luminescence of the Pt(II) complex crystal.

Graphical abstract: Liquid–liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(ii) complex

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Article information


Submitted
15 Jun 2020
Accepted
20 Sep 2020
First published
21 Sep 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Liquid–liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(II) complex

M. Kimura, M. Yoshida, S. Fujii, A. Miura, K. Ueno, Y. Shigeta, A. Kobayashi and M. Kato, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC04164E

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