Issue 71, 2020
From the journal:

Chemical Communications

All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters†

Jin-Hua Liu,a   Li-Dan Lin,a   Guo-Qiang Wang, ORCID logo b   Ling-Yun Li, ORCID logo b   Yan-Qiong Sun, ORCID logo a   Xin-Xiong Li ORCID logo *ac  and  Shou-Tian Zheng ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
E-mail: lxx@fzu.edu.cn, stzheng@fzu.edu.cn

b College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

c State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Abstract

A series of POM-based all-inorganic open frameworks, H9[Ln9W8(μ4-O)12(μ2-O)24(H2O)24](SiW12O40)3·60H2O (1-Ln, Ln = La, Pr and Nd), have been fabricated and structurally characterized for the first time. The unique architectures are constructed from nanoscale four-shell Ln@W8@Ln8@(SiW12)6 clusters. Additionally, the porous nature of the frameworks has also been investigated.

Graphical abstract: All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters

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Article information

DOI
https://doi.org/10.1039/D0CC04070C
Article type
Communication
Submitted
11 Jun 2020
Accepted
24 Jul 2020
First published
27 Jul 2020

Chem. Commun., 2020,56, 10305-10308

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All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters

J. Liu, L. Lin, G. Wang, L. Li, Y. Sun, X. Li and S. Zheng, Chem. Commun., 2020, 56, 10305 DOI: 10.1039/D0CC04070C

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