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Photocycloadditions in disparate chemical environments

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Abstract

We elucidate the wavelength dependence of a photocycloaddition by (i) accessing action plots dependent on the reactivity relative to the number of absorbed photons, (ii) establishing the effect on substrate concentration on photochemical reactivity and (iii) determining wavelength-dependent reactivity as a function of the solvent environment, comparing acetonitrile with dimethyl sulfoxide.

Graphical abstract: Photocycloadditions in disparate chemical environments

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Article information


Submitted
04 Jun 2020
Accepted
02 Oct 2020
First published
06 Oct 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Photocycloadditions in disparate chemical environments

D. E. Marschner, P. W. Kamm, H. Frisch, A. Unterreiner and C. Barner-Kowollik, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03911J

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