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Issue 67, 2020
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Control of local flexibility towards p-xylene sieving in Hofmann-type porous coordination polymers

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Abstract

Adsorption-based xylene isomer separation is more energy efficient than conventional processes. Herein, three isostructural Hofmann-type porous coordination polymers (PCPs), {M(Pz)[Ni(CN)4]n} (M = Fe, FePzNi, Co, CoPzNi, and Ni, NiPzNi; Pz = pyrazine) were synthesized and shown to exhibit coordination-dependent lability for the selectivity toward p-xylene over m- and o-xylene.

Graphical abstract: Control of local flexibility towards p-xylene sieving in Hofmann-type porous coordination polymers

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Supplementary files

Article information


Submitted
07 Jun 2020
Accepted
15 Jul 2020
First published
23 Jul 2020

Chem. Commun., 2020,56, 9632-9635
Article type
Communication

Control of local flexibility towards p-xylene sieving in Hofmann-type porous coordination polymers

M. Shivanna, K. Otake, J. Zheng, S. Sakaki and S. Kitagawa, Chem. Commun., 2020, 56, 9632
DOI: 10.1039/D0CC03854G

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