Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.



Intermediate snapshot on the insertion reaction of isocyanates into the Zn–Cp* bond of dizincocene Cp*2Zn2

Author affiliations

Abstract

Heteroleptic Zn(I) complexes Cp*Zn–Zn(N(R)C(Cp*)O) (R = Dipp = 2,6-i-Pr2-C6H3 2, t-Bu 3) with unsymmetrically η4-coordinated Cp* substituents represent snapshots of the insertion reaction of RNCO into the Zn–Cp* bond of Cp*2Zn2 1. The bonding situation in 2 and 3, which represent the first Zn(I) olefin complexes, was evaluated by computational calculation and further compared to other Zn(I) complexes.

Graphical abstract: Intermediate snapshot on the insertion reaction of isocyanates into the Zn–Cp* bond of dizincocene Cp*2Zn2

Back to tab navigation

Supplementary files

Article information


Submitted
30 May 2020
Accepted
24 Jun 2020
First published
24 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Intermediate snapshot on the insertion reaction of isocyanates into the Zn–Cp* bond of dizincocene Cp*2Zn2

B. Li, C. Wölper, K. Huse and S. Schulz, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03831H

Social activity

Search articles by author

Spotlight

Advertisements