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Issue 61, 2020
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Intermediate snapshot on the insertion reaction of isocyanates into the Zn–Cp* bond of dizincocene Cp*2Zn2

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Abstract

Heteroleptic Zn(I) complexes Cp*Zn–Zn(N(R)C(Cp*)O) (R = Dipp = 2,6-i-Pr2-C6H32, t-Bu 3) with unsymmetrically η4-coordinated Cp* substituents represent snapshots of the insertion reaction of RNCO into the Zn–Cp* bond of Cp*2Zn21. The bonding situation in 2 and 3, which represent the first Zn(I) olefin complexes, was evaluated by computational calculation and further compared to other Zn(I) complexes.

Graphical abstract: Intermediate snapshot on the insertion reaction of isocyanates into the Zn–Cp* bond of dizincocene Cp*2Zn2

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Supplementary files

Article information


Submitted
30 May 2020
Accepted
24 Jun 2020
First published
24 Jun 2020

Chem. Commun., 2020,56, 8643-8646
Article type
Communication

Intermediate snapshot on the insertion reaction of isocyanates into the Zn–Cp* bond of dizincocene Cp*2Zn2

B. Li, C. Wölper, K. Huse and S. Schulz, Chem. Commun., 2020, 56, 8643
DOI: 10.1039/D0CC03831H

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