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Issue 74, 2020
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Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

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Abstract

The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)2[Fe2(Cl2An)3]·(solv) (Cl2Ann = 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+ = tetrapropylammonium cation), by the site-doping of the Cl2Ann bridging unit using X2Ann units with X = Br or F.

Graphical abstract: Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

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Supplementary files

Article information


Submitted
29 May 2020
Accepted
06 Aug 2020
First published
07 Aug 2020

Chem. Commun., 2020,56, 10867-10870
Article type
Communication

Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers

Y. Sekine, J. Chen, N. Eguchi and H. Miyasaka, Chem. Commun., 2020, 56, 10867
DOI: 10.1039/D0CC03808C

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