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A large dinuclear Fe(ii) triple helicate demonstrating a two-step spin crossover

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Abstract

Reported herein, the synthesis as well as the structural and magnetic characterisation of the largest reported dinuclear Fe(II) triple helicate system to exhibit spin crossover—and also a rare example of a 273° helical twist using aromatic spacers—is presented, with exploration of the two-step spin-transition observed.

Graphical abstract: A large dinuclear Fe(ii) triple helicate demonstrating a two-step spin crossover

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Article information


Submitted
25 May 2020
Accepted
27 Jun 2020
First published
30 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A large dinuclear Fe(II) triple helicate demonstrating a two-step spin crossover

K. J. Howard-Smith, A. R. Craze, H. Zenno, J. Yagyu, S. Hayami and F. Li, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03708G

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