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Issue 74, 2020
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[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

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Abstract

Cluster anions [Cp*RuPb11]3− (1) and [Cu@Cp*RuPb11]2− (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo-clusters with C5v point symmetry and are static on the 207Pb NMR time scale in solution.

Graphical abstract: [Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

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Supplementary files

Article information


Submitted
24 Jun 2020
Accepted
06 Aug 2020
First published
06 Aug 2020

Chem. Commun., 2020,56, 10859-10862
Article type
Communication

[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra

A. Li, Y. Wang, P. Y. Zavalij, F. Chen, A. Muñoz-Castro and B. W. Eichhorn, Chem. Commun., 2020, 56, 10859
DOI: 10.1039/D0CC03656K

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