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Issue 86, 2020
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Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

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Abstract

Preliminary chemical reduction of naphthalenediimide (NDI)-based organic ligands was applied to the synthesis of a porous molecular conductor (PMC) with neutral metal nodes (cobalt(II) acetylacetonate). The obtained semiconductive PMC (PMC-2) was stable due to the neutral metal nodes, providing an advantage over electrochemical reduction.

Graphical abstract: Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

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Article information


Submitted
18 May 2020
Accepted
23 Sep 2020
First published
23 Sep 2020

Chem. Commun., 2020,56, 13109-13112
Article type
Communication

Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

S. Koyama, T. Tanabe, S. Takaishi, M. Yamashita and H. Iguchi, Chem. Commun., 2020, 56, 13109
DOI: 10.1039/D0CC03541F

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