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Abstract | Cited by

Herein, we report a protocol for visible-light-induced dearomative oxamination reactions of indole derivatives to afford functionalized spirocyclic products. These step-economical reactions, which involve C–N and C–O bond formation, feature mild conditions, a broad substrate scope, high yields, exclusive diastereoselectivity and step-economy. In addition, a similar protocol could be used to synthesize spirolactams by dearomative amidation of phenol derivatives.

Graphical abstract: Visible-light-induced dearomative oxamination of indole derivatives and dearomative amidation of phenol derivatives

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