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Modifying the luminescent properties of a Cu(i) diphosphine complex using ligand-centered reactions in single crystals

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Abstract

Here we report how reactions at a chemically reactive diphosphine shift the long-lived luminescent colour of a crystalline three-coordinate Cu(I) complex from green to blue. The results demonstrate how vapochromism and single-crystal-to-single-crystal transformations can be achieved using ligand-centered reactions.

Graphical abstract: Modifying the luminescent properties of a Cu(i) diphosphine complex using ligand-centered reactions in single crystals

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Article information


Submitted
13 May 2020
Accepted
30 Jun 2020
First published
30 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Modifying the luminescent properties of a Cu(I) diphosphine complex using ligand-centered reactions in single crystals

K. Lee, P. Lai, R. Parveen, C. M. Donahue, M. M. Wymore, B. A. Massman, B. Vlaisavljevich, T. S. Teets and S. R. Daly, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03427D

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