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Insertion of Ni(0) and Pd(0) precursors into the Si–Si bond of a disilane with two hypercoordinate silicon atoms

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Abstract

The activation of the silicon–silicon bond in disilane Ph2Si(μ-PzMe2)2SiPh2 (1), which possesses two five-coordinate silicon centers, was achieved by a reaction with Pd(0) or Ni(0) precursors of modest steric demand to afford a dinuclear Pd complex (2) or two types of mononuclear Ni complexes (3 and 4), respectively.

Graphical abstract: Insertion of Ni(0) and Pd(0) precursors into the Si–Si bond of a disilane with two hypercoordinate silicon atoms

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Article information


Submitted
04 May 2020
Accepted
19 Jun 2020
First published
22 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Insertion of Ni(0) and Pd(0) precursors into the Si–Si bond of a disilane with two hypercoordinate silicon atoms

R. Usui and Y. Sunada, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03211E

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