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Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO2 capture

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Abstract

An ultramicroporous MOF, ZU-36-Ni (GeFSIX-3-Ni) is obtained for the first time via a mechanochemical-assisted approach. The material exhibits excellent performance for trace CO2 capture (1.07 mmol g−1 at 400 ppm) and benchmark 50/50 CO2/CH4 selectivity of 930, which is proven by dynamic breakthrough tests.

Graphical abstract: Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO2 capture

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Article information


Submitted
04 May 2020
Accepted
12 Jun 2020
First published
13 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO2 capture

Z. Zhang, Q. Ding, S. B. Peh, D. Zhao, J. Cui, X. Cui and H. Xing, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03196H

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