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Overriding ortho selectivity by template assisted meta-C–H activation of benzophenones

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Abstract

An orthogonal selectivity for distal meta-C–H activation of benzophenone is acheived by overriding the inherent proximal ortho-selectivity through a template assisted metalation approach. This strategy has been successfully utilized in Pd-catalyzed regioselective C–C and C–Si bond formation.

Graphical abstract: Overriding ortho selectivity by template assisted meta-C–H activation of benzophenones

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Article information


Submitted
02 May 2020
Accepted
19 May 2020
First published
20 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Overriding ortho selectivity by template assisted meta-C–H activation of benzophenones

E. Casali, P. Kalra, M. Brochetta, T. Borsari, A. Gandini, T. Patra, G. Zanoni and D. Maiti, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03172K

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