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Issue 55, 2020
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N-Heterocyclic silylene/germylene ligands in Au(i) catalysis

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Abstract

Cationic Au(I) complexes (2, 5 and 8) supported by N-heterocyclic carbene, silylene and germylene ligands were prepared and their potential as catalysts in glycosidation chemistry has been evaluated. Insights into the mechanism are provided using DFT studies. Practical application of them as catalysts was achieved by the synthesis of the branched pentamannan core of the HIV-gp120 envelope under mild conditions.

Graphical abstract: N-Heterocyclic silylene/germylene ligands in Au(i) catalysis

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Article information


Submitted
01 May 2020
Accepted
01 Jun 2020
First published
01 Jun 2020

Chem. Commun., 2020,56, 7625-7628
Article type
Communication

N-Heterocyclic silylene/germylene ligands in Au(I) catalysis

N. Parvin, B. Mishra, A. George, M. Neralkar, J. Hossain, P. Parameswaran, S. Hotha and S. Khan, Chem. Commun., 2020, 56, 7625
DOI: 10.1039/D0CC03156A

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