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Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F2via oxidation of U(0) by SOF2

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Abstract

A fluoride stabilized sulfur-substituted uranyl complex [U(O)(S)F2] was prepared for the first time via oxidation of U(0) by SOF2 in cryogenic matrixes. The electron withdrawing character of F in this neutral complex does not cause the oxidation of the sulfido ligand by U(VI), but increases the strength and covalency of the U–O and U–S bonds.

Graphical abstract: Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F2 via oxidation of U(0) by SOF2

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Article information


Submitted
30 Apr 2020
Accepted
20 May 2020
First published
20 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F2 via oxidation of U(0) by SOF2

R. Wei, X. Chen and Y. Gong, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03139A

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