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Selective oxygenation of unactivated C–H bonds by dioxygen via the autocatalytic formation of oxoiron(v) species

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Abstract

Selective catalytic oxygenation of unactivated C–H bonds for a series of substrates by dioxygen using iron complexes was performed without the use of a co-reductant. Mechanistic studies indicate that the reaction proceeded via the autocatalytic formation of an oxoiron(V) intermediate, which brings high regioselectivity and stereoretention.

Graphical abstract: Selective oxygenation of unactivated C–H bonds by dioxygen via the autocatalytic formation of oxoiron(v) species

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Article information


Submitted
28 Apr 2020
Accepted
17 Jun 2020
First published
24 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Selective oxygenation of unactivated C–H bonds by dioxygen via the autocatalytic formation of oxoiron(V) species

B. Chandra, P. De and S. Sen Gupta, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03071F

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