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A closed-shell monomeric rhenium(1−) anion provided by m-terphenyl isocyanide ligation

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Abstract

The mixed isocyanide/carbonyl complexes cis- and trans-[Re(CO)3Br(CNArDipp2)2] (ArDipp2 = 2,6-(2,6-(i-Pr)2C6H3)2C6H3) can be synthesized from reactions of [Re(CO)5Br] and CNArDipp2 depending on the conditions applied. Reduction of the neutral Re(I) species gives the monoanionic complex [Re(CO)3(CNArDipp2)2] or the neutral [Re(CO)3(CNArDipp2)2], which contain rhenium in the formal oxidation states “−1” and “0”, respectively.

Graphical abstract: A closed-shell monomeric rhenium(1−) anion provided by m-terphenyl isocyanide ligation

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Supplementary files

Article information


Submitted
27 Apr 2020
Accepted
07 May 2020
First published
14 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A closed-shell monomeric rhenium(1−) anion provided by m-terphenyl isocyanide ligation

F. Salsi, M. Neville, M. Drance, A. Hagenbach, C. Chan, J. S. Figueroa and U. Abram, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC03043K

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