Issue 67, 2020

Two-step gas adsorption induced by the transmetallation in a two-dimensional metal–organic framework

Abstract

Transmetallation or replacement of Zn2+ ions with Cu2+ ions in a two-dimensional metal–organic framework, Zn3(TCPB)2(H2O)2 (H3TCPB = 1,3,5-tri(4-carboxyphenoxy)benzene), gives rise to additional gas adsorption, where the additional adsorption amount linearly depends on the degree of the transmetallation.

Graphical abstract: Two-step gas adsorption induced by the transmetallation in a two-dimensional metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
26 Apr 2020
Accepted
16 Jul 2020
First published
16 Jul 2020

Chem. Commun., 2020,56, 9727-9730

Two-step gas adsorption induced by the transmetallation in a two-dimensional metal–organic framework

H. J. Park, J. Oh, J. Kim and J. Kim, Chem. Commun., 2020, 56, 9727 DOI: 10.1039/D0CC03007D

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