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Luminescent ionic liquid formed from a melted rhenium(v) cluster

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Abstract

Recently, non-crystalline coordination materials have been shown to represent a versatile class of functional materials. However, such materials incorporating metal complex clusters have remained largely unexplored. Herein, we demonstrate that a luminescent tetranuclear ReV cluster melts at 489 K, with the cluster structure being maintained in the corresponding supercooled ionic liquid phase.

Graphical abstract: Luminescent ionic liquid formed from a melted rhenium(v) cluster

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Article information


Submitted
23 Apr 2020
Accepted
07 Jun 2020
First published
08 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Luminescent ionic liquid formed from a melted rhenium(V) cluster

J. Yanagisawa, T. Hiraoka, F. Kobayashi, D. Saito, M. Yoshida, M. Kato, F. Takeiri, G. Kobayashi, M. Ohba, L. F. Lindoy, R. Ohtani and S. Hayami, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02937H

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