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Synthesis of difluoromethylselenoesters from aldehydes via a radical process

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Abstract

Difluoromethylselenoester compounds, another important kind of organoselenium compounds, are reported herein for the first time. They can be efficiently synthesized from aldehydes and BnSeCF2H. The synthetic method features mild reaction conditions, broad substrate scope, good tolerance of functional groups, and importantly, no metal is involved in the reaction.

Graphical abstract: Synthesis of difluoromethylselenoesters from aldehydes via a radical process

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Article information


Submitted
22 Apr 2020
Accepted
23 Jun 2020
First published
24 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Synthesis of difluoromethylselenoesters from aldehydes via a radical process

R. Guo, X. Zhu, X. Zhang and Y. Wang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02912B

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