Issue 60, 2020

Tin-oxychalcogenide supertetrahedral clusters maintained in a MTN zeolite-analog arrangement by coulombic interactions

Abstract

Two crystalline salts, T3-SnOX-MTN (X = S/Se, MTN denotes a defined zeotype), both spatially assembled in an MTN net, have been fabricated. This was achieved by interlinking the isolated tin-oxychalcogenide tetrahedrally shaped clusters of T3-[Sn10O8X16]8− (X = S/Se) through coulombic interactions with protonated organic amine templates. T3-SnOX-MTN (X = S/Se), with 74.1/76.5 Å cubic unit-cell axial-lengths, have a proton-conductivity of over 10−3 S cm−1 under 98% relative humidity at 50 °C.

Graphical abstract: Tin-oxychalcogenide supertetrahedral clusters maintained in a MTN zeolite-analog arrangement by coulombic interactions

Supplementary files

Article information

Article type
Communication
Submitted
22 Apr 2020
Accepted
15 Jun 2020
First published
16 Jun 2020

Chem. Commun., 2020,56, 8388-8391

Tin-oxychalcogenide supertetrahedral clusters maintained in a MTN zeolite-analog arrangement by coulombic interactions

M. Luo, S. Huang, H. Lai, J. Zhang and Q. Lin, Chem. Commun., 2020, 56, 8388 DOI: 10.1039/D0CC02909B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements