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Tin-oxychalcogenide supertetrahedral clusters maintained in a MTN zeolite-analog arrangement by coulombic interactions

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Abstract

Two crystalline salts, T3-SnOX-MTN (X = S/Se, MTN denotes a defined zeotype), both spatially assembled in an MTN net, have been fabricated. This was achieved by interlinking the isolated tin-oxychalcogenide tetrahedrally shaped clusters of T3-[Sn10O8X16]8− (X = S/Se) through coulombic interactions with protonated organic amine templates. T3-SnOX-MTN (X = S/Se), with 74.1/76.5 Å cubic unit-cell axial-lengths, have a proton-conductivity of over 10−3 S cm−1 under 98% relative humidity at 50 °C.

Graphical abstract: Tin-oxychalcogenide supertetrahedral clusters maintained in a MTN zeolite-analog arrangement by coulombic interactions

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Supplementary files

Article information


Submitted
22 Apr 2020
Accepted
15 Jun 2020
First published
16 Jun 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Tin-oxychalcogenide supertetrahedral clusters maintained in a MTN zeolite-analog arrangement by coulombic interactions

M. Luo, S. Huang, H. Lai, J. Zhang and Q. Lin, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02909B

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