Issue 57, 2020
From the journal:

Chemical Communications

A bicyclic unit reversal to stabilize the 12/14-helix in mixed homochiral oligoureas†

Pierre Milbeo, ORCID logo a   Matthieu Simon,a   Claude Didierjean,b   Emmanuel Wenger, ORCID logo b   Emmanuel Aubert,b   Jean Martinez, ORCID logo a   Muriel Amblard,a   Monique Calmès*a  and  Baptiste Legrand ORCID logo *a  

* Corresponding authors

a Institut des Biomolécules Max Mousseron, IBMM, University of Montpellier, ENSCM, CNRS, Montpellier, France
E-mail: baptiste.legrand@umontpellier.fr, monique.calmes@gmail.com

b Université de Lorraine, CNRS, Nancy, France

Abstract

The insertion of cyclic building blocks in oligoureas to stabilize or modulate the properties of the 12/14-helix was often fruitless. We herein propose a fully compatible highly constrained building block that could be incorporated into oligoureas to develop highly stable and functional oligoureas helices.

Graphical abstract: A bicyclic unit reversal to stabilize the 12/14-helix in mixed homochiral oligoureas

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Article information

DOI
https://doi.org/10.1039/D0CC02902E
Article type
Communication
Submitted
22 Apr 2020
Accepted
27 May 2020
First published
27 May 2020

Chem. Commun., 2020,56, 7921-7924

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A bicyclic unit reversal to stabilize the 12/14-helix in mixed homochiral oligoureas

P. Milbeo, M. Simon, C. Didierjean, E. Wenger, E. Aubert, J. Martinez, M. Amblard, M. Calmès and B. Legrand, Chem. Commun., 2020, 56, 7921 DOI: 10.1039/D0CC02902E

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