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Modulated synthesis and isoreticular expansion of Th-MOFs with record high pore volume and surface area for iodine adsorption

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Abstract

Modulated synthesis and isoreticular expansion of Th-MOFs enable the stepwise construction of hierarchical complexes in which porosity and functionality can be fine-tuned, affording new Th-MOFs with a record high void space (74.0%), the largest surface area (3396.5 m2 g−1) among thorium materials, and excellent adsorption capacities toward radioactive iodine.

Graphical abstract: Modulated synthesis and isoreticular expansion of Th-MOFs with record high pore volume and surface area for iodine adsorption

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Article information


Submitted
20 Apr 2020
Accepted
10 May 2020
First published
11 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Modulated synthesis and isoreticular expansion of Th-MOFs with record high pore volume and surface area for iodine adsorption

Z. Li, Y. Ju, B. Yu, X. Wu, H. Lu, Y. Li, J. Zhou, X. Guo, Z. Zhang, J. Lin, J. Wang and S. Wang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02841J

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