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Reversible control of ionic conductivity and viscoelasticity of organometallic ionic liquids by application of light and heat

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Abstract

Ru-containing ionic liquids [Ru(C5H5){C6H3(OC6H12CN)3}][N(SO2F)2] (1) and [Ru(C5H5){C6H5(OC3H6CN)}][N(SO2F)2] (2), having different numbers of substituents, were reversibly converted to coordination polymer solids and oligomeric liquids, respectively, by UV photoirradiation and heating. This feature enabled the control of their ionic conductivities and viscoelastic properties.

Graphical abstract: Reversible control of ionic conductivity and viscoelasticity of organometallic ionic liquids by application of light and heat

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Article information


Submitted
17 Apr 2020
Accepted
12 May 2020
First published
12 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Reversible control of ionic conductivity and viscoelasticity of organometallic ionic liquids by application of light and heat

R. Sumitani, H. Yoshikawa and T. Mochida, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02786C

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