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Issue 54, 2020
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Nickel-catalyzed allyl–allyl coupling reactions between 1,3-dienes and allylboronates

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Abstract

A regiospecific allyl–allyl coupling reaction between 1,3-dienes and allylboronates has been demonstrated under nickel catalysis. Salient features of this method include the earth-abundant metal catalyst, excellent regioselectivity and good functional group tolerance. Notably, even congested allyl substrates can also be applied to this protocol, thus allowing for the rapid preparation of a series of valuable 1,5-dienes.

Graphical abstract: Nickel-catalyzed allyl–allyl coupling reactions between 1,3-dienes and allylboronates

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Submitted
14 Apr 2020
Accepted
26 May 2020
First published
26 May 2020

Chem. Commun., 2020,56, 7431-7434
Article type
Communication

Nickel-catalyzed allyl–allyl coupling reactions between 1,3-dienes and allylboronates

D. Ji, G. He, W. Zhang, C. Zhao, Y. Hu and Q. Chen, Chem. Commun., 2020, 56, 7431
DOI: 10.1039/D0CC02697B

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