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Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au

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Abstract

A novel Pd/Au vinylene complex synthesized through cyclization of σ,π-heterodinuclear (Pd/Au) acetylide reacted with iodobenzene to give a Pd vinyl species, where the presence of a strong metallophilic Pd⋯Au interaction was found to facilitate phenyl transmetalation from Pd to Au, followed by reductive elimination at Au.

Graphical abstract: Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au

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Article information


Submitted
13 Apr 2020
Accepted
17 Apr 2020
First published
17 Apr 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au

J. Wang, L. Zhan, G. Wang, Y. Wei, M. Shi and J. Zhang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02645J

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