Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 43, 2020
Previous Article Next Article

Double-layered honeycomb architectures constructed via hierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

Author affiliations

Abstract

A hexagonal cobalt(II) metallacycle and its “lipid packaged” derivatives, [Co6(R-bisterpy)6]X12 (R = H, OC16H33, OC27H55; X = BF4, C12-Glu), have been synthesized and characterized. The compounds incorporating BF4 anions formed sphere-like aggregates while the compounds with C12-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.

Graphical abstract: Double-layered honeycomb architectures constructed via hierarchical self-assembly of hexagonal spin crossover cobalt(ii) metallacycles

Back to tab navigation

Supplementary files

Article information


Submitted
11 Apr 2020
Accepted
16 Apr 2020
First published
16 Apr 2020

Chem. Commun., 2020,56, 5835-5838
Article type
Communication

Double-layered honeycomb architectures constructed via hierarchical self-assembly of hexagonal spin crossover cobalt(II) metallacycles

R. Akiyoshi, K. Kuroiwa, M. Sakuragi, S. Yoshimoto, R. Ohtani, M. Nakamura, L. F. Lindoy and S. Hayami, Chem. Commun., 2020, 56, 5835
DOI: 10.1039/D0CC02628J

Social activity

Search articles by author

Spotlight

Advertisements