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Issue 54, 2020
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Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine–dioxime catalysts under both aqueous and organic conditions

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Abstract

The photocatalytic generation of an NADH synthetic analogue, i.e. 1-benzyl-1,4-dihydronicotinamide (1,4-BNAH), has been studied using the cobalt diimino–dioxime complexes and the BF2-bridged derivative as catalysts. 1,4-BNAH was produced in both aqueous and organic media at unprecedented turnover numbers with metal and organic photosensitizers, respectively.

Graphical abstract: Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine–dioxime catalysts under both aqueous and organic conditions

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Article information


Submitted
10 Apr 2020
Accepted
25 May 2020
First published
27 May 2020

Chem. Commun., 2020,56, 7491-7494
Article type
Communication

Precious-metal free photocatalytic production of an NADH analogue using cobalt diimine–dioxime catalysts under both aqueous and organic conditions

C. Kwok, S. Cheng, P. Ho, S. Yiu, W. Man, V. K. Au, P. Tsang, C. Leung, C. Ko and M. Robert, Chem. Commun., 2020, 56, 7491
DOI: 10.1039/D0CC02604B

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