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ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping

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Abstract

Compounds bearing ortho-oriented dialkylamino and boryl groups can serve as efficient reagents to trap difluorocarbene leading to zwitterionic ammonium borates featuring N-CF2-B fragments. The reagents are shelf-stable and can be used as mechanistic probes for reactions proceeding via difluorocarbene.

Graphical abstract: ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping

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Article information


Submitted
09 Apr 2020
Accepted
20 May 2020
First published
20 May 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping

E. A. Ilin, V. O. Smirnov, A. D. Volodin, A. A. Korlyukov and A. D. Dilman, Chem. Commun., 2020, Advance Article , DOI: 10.1039/D0CC02567D

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